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http://ipicyt.repositorioinstitucional.mx/jspui/handle/1010/2250| Influence of protons on reduction degree and defect formation in electrochemically reduced graphene oxide | |
| JAVIER ALAN QUEZADA RENTERIA Ania Conchi O. Luis Felipe Cházaro Ruiz JOSE RENE RANGEL MENDEZ | |
| Acceso Abierto | |
| Atribución-NoComercial-SinDerivadas | |
| https://doi.org/10.1016/j.carbon.2019.04.109 | |
| Graphene oxide Electrochemical reduction Reduced graphene oxide Defects | |
| "The electrochemical reduction of GO was investigated in aqueous, at both acid and basic pH, and organic media, to identify the possible role of protons (H+) in the reduction mechanism of this material. The obtained rGO films were characterized by FTIR, electrochemical methods, Raman and XPS spectroscopy. Data showed that the reduction was more efficient in acid and basic media due to the presence of protons and the capacity of water that works as a proton donor, resulting in C/O ratios of 3.8 and 7.8, respectively. Mostly hydroxyl, epoxide and carbonyl moieties were removed. In a proton-free organic electrolyte, a C/O ratio of 1.8 was obtained for most of the samples; nevertheless, the graphitic carbon sp2 domains were restored to a large extent in the absence of H+. The characterization of the material showed that the presence of protons, during the electrochemical reduction, caused hydrogenation reactions, which targeted the graphitic domains in rGO and resulted in the loss of sp2 hybridization. The presence of such defects modified the electrochemical properties of the rGO films, where, despite of exhibiting higher C/O ratio, the films reduced in aqueous electrolytes displayed lower electron transfer (e.g. ferrocyanide redox-probe) than those reduced in organic electrolyte." | |
| Elsevier | |
| 2019 | |
| Artículo | |
| Javier A. Quezada-Renteria, Conchi O. Ania, Luis F. Chazaro-Ruiz, Jose R. Rangel-Mendez, Influence of protons on reduction degree and defect formation in electrochemically reduced graphene oxide, Carbon, Volume 149, 2019, Pages 722-732, https://doi.org/10.1016/j.carbon.2019.04.109. | |
| QUÍMICA | |
| Versión publicada | |
| publishedVersion - Versión publicada | |
| Aparece en las colecciones: | Publicaciones Científicas Ciencias Ambientales |
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| Carbon149(2019)722.pdf | 2.68 MB | Adobe PDF | Visualizar/Abrir |