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Effect of ball to powder ratio on the mechanosynthesis of Re2C and its compressibility
ALFREDO MARTINEZ GARCIA
ANA KARIN NAVARRO MARTINEZ
Christopher Neun
Lkhamsuren Bayarjargal
Wolfgang Morgenroth
ERICK LOPEZ VAZQUEZ
MIGUEL AVALOS BORJA
Bjoern Winkler
Erick Adrián Juárez Arellano
En Embargo
30-11-2021
Atribución-NoComercial-SinDerivadas
https://doi.org/10.1016/j.jallcom.2019.151867
Rhenium carbide
High-energy ball-milling
Compressibility
Metastable phase
Accumulated energy
"The mechanosynthesis of hexagonal rhenium carbide (Re2C) from the elements is explored as a function of the balls to powder ratio (BPR). Burgios's equation has been used to calculate the accumulated energy (Delta E-accum) and the transferred energy per hit (Delta E-b). To get the complete mechanosynthesis of Re2C several conditions have to be met: BPR > 115: 1, Delta E-accum > 500 kJ/g, and Delta E-b > 2.656 x 10(-14) kJ. The reaction is completed after 30 min of milling if a BPR of 230: 1 is used. The pressure dependence of the unit-cell volume and the lattice parameters have been evaluated by synchrotron radiation diffraction using a diamond anvil cell up to 61(2) GPa. A fit of a 2nd-order Birch-Murnaghan equation of state results in a bulk modulus of B-0 = 374(3) GPa."
Elsevier
2019
Artículo
A. Martinez-Garcia, A.K. Navarro-Mtz, C. Neun, L. Bayarjargal, W. Morgenroth, E. Lopez-Vazquez, M. Avalos-Borja, B. Winkler, E.A. Juarez-Arellano, Effect of ball to powder ratio on the mechanosynthesis of Re2C and its compressibility, Journal of Alloys and Compounds, Volume 810, 2019, 151867, https://doi.org/10.1016/j.jallcom.2019.151867.
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Aparece en las colecciones: Publicaciones Científicas Nanociencias y Materiales