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Adsorption of molecular gases on porous materials in the SAFT-VR approximation
HARET CODRATIAN ROSU
Acceso Abierto
Atribución-NoComercial-SinDerivadas
https://doi.org/10.1016/j.physa.2010.04.028
Adsorption
Statistical associating fluid
Helmholtz free energy
Porous material
"A simple molecular thermodynamic approach is applied to the study of the adsorption of gases of chain molecules on solid surfaces. We use a model based on the Statistical Associating Fluid Theory for Variable Range (SAFT-VR) potentials [A. Gil-Villegas, A. Galindo, P. J. Whitehead, S. J. Mills, G. Jackson, A. N. Burgess, J. Chem. Phys. 106 (1997) 4168] that we extend by including a quasi-two-dimensional approximation to describe the adsorption properties of this type of real gases [A. Mart´ınez, M. Castro, C. McCabe, A. Gil-Villegas, J. Chem. Phys. 126 (2007) 074707]. The model is applied to ethane, ethylene, propane, and carbon dioxide adsorbed on activated carbon and silica gel, which are porous media of significant industrial interest. We show that the adsorption isotherms obtained by means of the present SAFT-VR modeling are in fair agreement with the experimental results provided in the literature."
Elsevier
2010
Artículo
Inglés
Público en general
M. Castro, R. Martinez, A. Martinez, H.C. Rosu, Adsorption of molecular gases on porous materials in the SAFT-VR approximation, Physica A: Statistical Mechanics and its Applications, Volume 389, Issue 16, 2010, Pages 3140-3148, ISSN 0378-4371, http://dx.doi.org/10.1016/j.physa.2010.04.028.
CIENCIAS FÍSICO MATEMÁTICAS Y CIENCIAS DE LA TIERRA
Versión aceptada
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Aparece en las colecciones: Publicaciones Científicas Nanociencias y Materiales

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