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SERS properties of different sized and shaped gold nanoparticles biosynthesized under different environmental conditions by Neurospora crassa extract
KATRIN QUESTER
MIGUEL AVALOS BORJA
ALFREDO RAFAEL VILCHIS NESTOR
MARCO ANTONIO CAMACHO LOPEZ
ERNESTINA CASTRO LONGORIA
Acceso Abierto
Atribución-NoComercial-SinDerivadas
https://doi.org/10.1371/journal.pone.0077486
"Surface-enhanced Raman scattering (SERS) is a surface-sensitive technique that enhances Raman scattering by molecules adsorbed on rough metal surfaces. It is known that metal nanoparticles, especially gold and silver nanoparticles, exhibit great SERS properties, which make them very attractive for the development of biosensors and biocatalysts. On the other hand, the development of ecofriendly methods for the synthesis of metallic nanostructures has become the focus of research in several countries, and many microorganisms and plants have already been used to biosynthesize metallic nanostructures. However, the majority of these are pathogenic to plants or humans. Here, we report gold nanoparticles with good SERS properties, biosynthesized by Neurospora crassa extract under different environmental conditions, increasing Raman signals up to 40 times using methylene blue as a target molecule. Incubation of tetrachloroauric acid solution with the fungal extract at 60 degrees C and a pH value of a) 3, b) 5.5, and c) 10 resulted in the formation of gold nanoparticles of a) different shapes like triangles, hexagons, pentagons etc. in a broad size range of about 10-200 nm, b) mostly quasi-spheres with some different shapes in a main size range of 6-23 nm, and c) only quasi-spheres of 3-12 nm. Analyses included TEM, HRTEM, and EDS in order to corroborate the shape and the elemental character of the gold nanoparticles, respectively. The results presented here show that these 'green' synthesized gold nanoparticles might have potential applicability in the field of biological sensing."
Public Library of Science
2013-10
Artículo
Inglés
Público en general
Quester K, Avalos-Borja M, Vilchis-Nestor AR, Camacho-López MA, Castro-Longoria E (2013) SERS Properties of Different Sized and Shaped Gold Nanoparticles Biosynthesized under Different Environmental Conditions by Neurospora crassa Extract. PLoS ONE 8(10): e77486. https://doi.org/10.1371/journal.pone.0077486
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Aparece en las colecciones: Publicaciones Científicas Nanociencias y Materiales

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