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Silver nanoparticles loaded on Cu-doped TiO2 for the effective reduction of nitro-aromatic contaminants
Agileo Hernández Gordillo
VICENTE RODRIGUEZ GONZALEZ
Acceso Abierto
Atribución-NoComercial-SinDerivadas
https://doi.org/10.1016/j.cej.2014.05.148
Hydrazine reagent
4-Nitrophenol reduction
Cu-doped TiO2
AgNPs photoactivity
Copper glycine complexes
"The addition of Cu species via copper glycine complexes as a strategy for doping the TiO2 structure during the sol–gel process produces a copper–TiO2-based composite. The combination of the copper–TiO2-based composite with the practical UV functionalization of highly dispersed silver nanoparticles (AgNPs), 3 nm, results in an efficient photocatalyst for eliminating 4-nitrophenol as a model of nitro-aromatic contaminant. This novel Ag/TiO2–Cu composite achieved the effective photoreduction of 4-nitrophenol into the valuable 4-aminophenol in approximately 30 min with high conversion (96%). A possible reduction mechanism of aromatic nitro compounds into amines in aqueous alkaline medium is discussed, considering the interfacial fast charge transfer during the in situ reduction of copper by the presence of hydrazine as a sacrificial electron donor."
Elsevier
2015
Artículo
Agileo Hernández-Gordillo, Vicente Rodríguez González, Silver nanoparticles loaded on Cu-doped TiO2 for the effective reduction of nitro-aromatic contaminants, Chemical Engineering Journal, Volume 261, 2015, Pages 53-59.
QUÍMICA
Versión aceptada
acceptedVersion - Versión aceptada
Aparece en las colecciones: Publicaciones Científicas Nanociencias y Materiales

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