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Synthesis and magnetocaloric characterization of rapidly solidified ErMn2 melt-spun ribbons
JOSE LUIS SANCHEZ LLAMAZARES
Pablos Jesús Ibarra Gaytán
CESAR FIDEL SANCHEZ VALDES
Pablo Álvarez Alonso
ARMANDO DAVID MARTINEZ INIESTA
Acceso Abierto
Atribución-NoComercial-SinDerivadas
https://doi.org/10.1016/j.intermet.2017.05.001
ErMn2 Laves phase
Melt spun ribbons
Magnetocaloric effect
Magnetic entropy change
Adiabatic temperature change
"We have fabricated melt-spun ribbons of nominal composition ErMn2 and studied their phase constitution and magnetocaloric (MC) properties by X-ray diffraction, scanning electron microscopy (SEM), magnetization and heat capacity measurements. The major phase formed shows the MgZn2-type hexagonal structure (C14-type); however, both XRD and SEM analyses revealed the formation of impurity phases (i.e., Er6Mn23 and ErMn12). Ribbons exhibit a saturation magnetization of 149 Am2kg?1 at 2 K and a Curie temperature of TC = 15 K. A field-induced metamagnetic transition at very low critical magnetic fields was observed below 8 K that leads to a change of sign in the magnetic entropy change ?SM below this temperature (?SMpeak = 2.5 Jkg?1K?1 at 2 K and 5 T). For a magnetic field change of 5 T (2 T) applied along the ribbon length, the samples show a large peak value of the magnetic entropy change ?SMpeak of ?20.5 (?10.8) Jkg?1K?1, a full-width at half-maximum ?TFWHM for the ?SM(T) curve of 20 (12) K, and a maximum adiabatic temperature change ?Tadmax of 7.4 (3.6) K. The obtained results are compared with the reported in literature by other authors for bulk alloys."
Elsevier
2017
Artículo
J.L. Sánchez Llamazares, P. Ibarra-Gaytán, C.F. Sánchez-Valdés, P. Álvarez-Alonso, A.D. Martínez-Iniesta, Synthesis and magnetocaloric characterization of rapidly solidified ErMn2 melt-spun ribbons, Intermetallics, Volume 88, 2017, Pages 41-45.
QUÍMICA
Versión revisada
submittedVersion - Versión revisada
Aparece en las colecciones: Publicaciones Científicas Nanociencias y Materiales

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