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http://ipicyt.repositorioinstitucional.mx/jspui/handle/1010/2130| Compressibility, microcalorimetry, elastic properties and EELS of rhenium borides | |
| Christopher Neun Benedikt Petermueller Lkhamsuren Bayarjargal Wolfgang Morgenroth MIGUEL AVALOS BORJA Héctor Gabriel Silva Pereyra Dominik Spahr Felix Schmuck Victor Milman Hubert Huppertz Bjoern Winkler | |
| En Embargo | |
| 31-12-2020 | |
| Atribución-NoComercial-SinDerivadas | |
| https://doi.org/10.1016/j.solidstatesciences.2018.02.016 | |
| Transition metal borides Elastic properties High-pressure XRD Microcalorimetry EELS Density functional theory | |
| "Based on synchrotron X-ray diffraction on phase-pure samples, we revised the bulk moduli of the rhenium borides Re7B3 (B-0 (Re7B3) = 391(5) GPa) and orthorhombic Re3B (B-0 (orthorhombic Re3B) = 393(4) GPa) and determined the bulk modulus of monoclinic Re3B (B-0 (monoclinic Re3B) = 390(3) GPa). These results agree well with the DFT calculations on the elastic properties. Microcalorimetry was employed to obtain thermodynamic data for Re7B3 and orthorhombic Re3B and we determined C-P,(298) (Re7B3) = 210(4) J/mol, Delta H-2(98)0 (Re7B3) = 40558(400) J/mol, S-298(0) (Re7B3) = 267(2) J/mol K and theta(D)(,)(298) (Re7B3) = 320(2) K, as well as C-p,(298) (Re3B)= 86(1) J/mol, Delta H-2(98)0 (Re3B) = 16950(170) J/mol, S-2(98)0 (Re3B) 112(1) J/mol K and theta(D,)(298) (Re3B) = 329(3) K. Hardness measurements were performed for Re7B3, which gave a Vickers hardness H-V(5 kgf) = 14.5(4) GPa and H-V(10 kgf) = 14.1(3) GPa. Electron energy loss spectroscopy (EELS) was performed on orthorhombic Re3B and ReB2, and the experimental spectra are well reproduced by theory in terms of their absorption edges." | |
| Elsevier | |
| 2018 | |
| Artículo | |
| Christopher Neun, Benedikt Petermüller, Lkhamsuren Bayarjargal, Wolfgang Morgenroth, Miguel Avalos-Borja, Hector G. Silva-Pereyra, Dominik Spahr, Felix Schmuck, Victor Milman, Hubert Huppertz, Björn Winkler, Compressibility, microcalorimetry, elastic properties and EELS of rhenium borides, Solid State Sciences, Volume 81, 2018, Pages 71-81. | |
| QUÍMICA | |
| Versión aceptada | |
| acceptedVersion - Versión aceptada | |
| Aparece en las colecciones: | Publicaciones Científicas Nanociencias y Materiales |