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One-Pot Synthesis of Anatase, Rutile-Decorated Hydrogen Titanate Nanorods by Yttrium Doping for Solar H2 Production
Sovann khan
Hiroshi Ikari
Norihiro Suzuki
Kazuya Nakata
Chiaki Terashima
Akira Fujishima
Ken-ichi Katsumata
VICENTE RODRIGUEZ GONZALEZ
Acceso Abierto
Atribución-NoComercial-SinDerivadas
https://doi.org/10.1021/acsomega.0c02855
"We have prepared yttrium (Y)-doped hydrogen titanate nanorods (HTN) by a microwave-assisted hydrothermal method. Y-doped HTN showed much improved photocatalytic activities for both H2 evolution and dye decomposition. H2 production from a methanol–water solution under UV–visible light for 7 h was enhanced by a factor of 5.5 with 1 wt % Y-doping. Doping with Y3+ ions reduced the band gap of HTN by ∼0.28 eV and induced new phases of anatase and rutile. High photocatalysis by Y-doping was attributed to enhanced light absorption (smaller band gap) and effective charge separation (heterojunction). To optimize H2 production, a series of experiments examining effects of doping concentrations and non-noble surface metal (e.g., Ni, Cu, Co) loading were carefully performed. Y-doping in this work is a new and promising approach for synthesizing highly active HTN by producing the HTN/rutile/anatase heterostructure within the one-pot method."
American Chemical Society
2020
Artículo
ACS Omega 2020, 5, 36, 23081–23089 Publication Date:August 31, 2020 https://doi.org/10.1021/acsomega.0c02855 Copyright © 2020 American Chemical Society
QUÍMICA
Versión publicada
publishedVersion - Versión publicada
Aparece en las colecciones: Publicaciones Científicas Nanociencias y Materiales

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